The Gas-Phase Smiles Rearrangement: A Heavy Atom Labeling Study

DOI: 10.1021/ja00194a011

Source and publish data:

Journal of the American Chemical Society p. 4224 - 4227 (1989)

Update date:2022-07-30

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Authors:

Eichinger, Peter C.H.

Bowie, John H.

Hayes, Roger N.

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Article abstract of DOI:10.1021/ja00194a011

Heavy atom ((13)C and (18)O) labeling shows that the product ion PhO^- from PhO(CH2)2O^- and products PhO^- and PhS^- from PhS(CH2)2O^- are formed through Smiles intermediates I (X=Y=O or X=O, Y=S).The ana

Full text of DOI:10.1021/ja00194a011

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