Application of Free Radical Substitution Reaction into Interconversion of 1-Alkenylsulfides, 1-Alkenylgermanes, and 1-Alkenylstannanes

DOI: 10.1246/cl.1988.669

Source and publish data:

Chemistry Letters p. 669 - 672 (1988)

Update date:2022-08-04

Topics:

Authors:

Ichinose, Yoshifumi

Oshima, Koichiro

Utimoto, Kiitiro

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Article abstract of DOI:10.1246/cl.1988.669

Treatment of 1-alkenylsulfides or 1-alkenylstannanes with Ph3GeH in the presence of Et3B provides 1-alkenyltriphenylgermanes in good yields. 1-Alkenylstannanes are converted into 1-alkenylsulfides easily with PhSH-Et3B, whereas 1-alkenyltriphenylgermanes are recovered unchanged upon treatment with Ph3SnH-Et3B or PhSH-Et3B.

Full text of DOI:10.1246/cl.1988.669

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