Chemistry Letters p. 669 - 672 (1988)
Update date:2022-08-04
Topics:
Ichinose, Yoshifumi
Oshima, Koichiro
Utimoto, Kiitiro
Treatment of 1-alkenylsulfides or 1-alkenylstannanes with Ph3GeH in the presence of Et3B provides 1-alkenyltriphenylgermanes in good yields. 1-Alkenylstannanes are converted into 1-alkenylsulfides easily with PhSH-Et3B, whereas 1-alkenyltriphenylgermanes are recovered unchanged upon treatment with Ph3SnH-Et3B or PhSH-Et3B.
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