Organic Letters p. 820 - 823 (2010)
Update date:2022-08-04
Topics:
Mossetti, Riccardo
Pirall, Tracey
Tron, Gian Cesare
Zhu, Jieping
"Chemical equation presented" Acyl chlorides and α-isocyanoacetamides undergo an efficient reaction in dichloromethane in the presence of triethylamine to give 2-acyl5-aminooxazoles. Subsequent acid hydrolysis of the 5-aminooxazole moiety leads to α-ketoamides in good overall yields.
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