ASYMMETRIC HYDROGENATION OF ACTIVATED KETO COMPOUNDS CATALYZED BY NEW CHIRAL PERALKYL-AMPP RHODIUM COMPLEXES

DOI: 10.1016/S0040-4039(00)82151-6

Source and publish data:

Tetrahedron Letters p. 3675 - 3678 (1988)

Update date:2022-08-03

Topics:

Authors:

Hatat, Corinne

Karim, Abdallah

Kokel, Nicolas

Mortreux, Andre

Petit, Francis

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Article abstract of DOI:10.1016/S0040-4039(00)82151-6

Readily available peralkyl aminophosphinephosphinite ligands (alkyl-AMPP) give neutral rhodium complexes active for the catalytic reduction of some activated ketones under atmospheric hydrogen pressure at ambient temperature (ee=80percent).

Full text of DOI:10.1016/S0040-4039(00)82151-6

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