General Reactivity of 2-Lithiobenzothiazole to Various Electrophiles and the Use as a Formyl Anion Equivalent in the Synthesis of α-Hydroxy Carbonyl Compounds

DOI: 10.1246/bcsj.61.3637

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3637 - 3648 (1988)

Update date:2022-08-02

Topics:

Authors:

Chikashita, Hidenori

Ishibaba, Megumi

Ori, Keiji

Itoh, Kazuyoshi

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Article abstract of DOI:10.1246/bcsj.61.3637

The reaction of 2-lithiobenzothiazole with a variety of electrophiles such as aldehydes, ketones, carboxylic esters, lactones, nitriles, and amides afforded the expected addition and substitution products.Trimethylsilyl chloride readily reacted with the b

Full text of DOI:10.1246/bcsj.61.3637

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