Palladium-Catalyzed 'Metallo-Ene'-Type Cyclization/Vinylstannane Coupling of 1-Acetoxy-octa-2,7-dienes and 1-Acetoxy-oct-2-en-7-ynes

DOI: 10.1002/hlca.19930760313

Source and publish data:

Helvetica Chimica Acta p. 1266 - 1274 (1993)

Update date:2022-08-03

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Authors:

Oppolzer, Wolfgang

Ruiz-Montes, Jose

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Article abstract of DOI:10.1002/hlca.19930760313

Palladiumbis(dibenzylideneacetone)/tri(2-furyl)phosphine-catalyzed cyclizations of dienyl acetates 2 in the presence of an (1-alkenyl)(tributyl)stannane and ZnCl2 provided trans-substituted 3-alkenyl-4-vinylcyclopentanes 11 in good yields.Analogous intram

Full text of DOI:10.1002/hlca.19930760313

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