Tetrahedron p. 6021 - 6030 (1988)
Update date:2022-08-02
Topics:
Naruse, Yuji
Yamamoto, Hisashi
Employing the homochiral acetal template, asymmetrization of meso-substituted cyclohexanones is explored.By the use of optically-active 2,4-pentanediol as a chiral protecting group, highly diastereoselective acetal cleavage is achieved when treated with organoaluminum reagent.Dialkylaluminum amides are also effective reagents for this reaction.
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