A GENERAL SYNTHETIC APPROACH TO OPTICALLY ACTIVE IRIDOID AGLYCONES. THE TOTAL SYNTHESES OF β-ETHYL DESCARBOMETHOXYVERBENALOL, ETHYL CATALPOL, AND (-)-SPECIONIN

DOI: 10.1016/S0040-4020(01)85940-8

Source and publish data:

Tetrahedron p. 3079 - 3092 (1988)

Update date:2022-08-04

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Authors:

Kim, Byeang Hyean

Jacobs, Patricia B.

Elliott, Richard L.

Curran, Dennis P.

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Article abstract of DOI:10.1016/S0040-4020(01)85940-8

A general approach to the synthesis of iridoid aglycones is reported.A combination Claisen rearrangement/nitrile oxide cycloaddition sequence has permitted the facile annulation of a highly functionalized cyclopentane ring onto a simple glycal derived fro

Full text of DOI:10.1016/S0040-4020(01)85940-8

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