A REGIO- AND STEREOSELECTIVE SYNTHESIS OF SUBSTITUTED PIPERIDONES

DOI: 10.1016/S0040-4039(00)82280-7

Source and publish data:

Tetrahedron Letters p. 6115 - 6118 (1988)

Update date:2022-07-29

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Authors:

Bayard, Philippe

Ghosez, Leon

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Article abstract of DOI:10.1016/S0040-4039(00)82280-7

The new activated 2-aza-1,3-dienes 1 are readily prepared by acylation of N-trimethylsilylimines 3.They react with electrophilic olefins to yield substituted piperidones 4 and 6 with high diastereoselectivity.

Full text of DOI:10.1016/S0040-4039(00)82280-7

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