Acta Crystallographica, Section C: Crystal Structure Communications p. 1623 - 1625 (1999)
Update date:2022-07-30
Topics:
Suenaga, Yusaku
Kuroda-Sowa, Takayoshi
Maekawa, Masahiko
Munakata, Megumu
The silver(I) complex of tetrakis(isopropylthio)-p-benzoquinone (tpq), catena-poly[silver(I)-μ-[2,3,5,6-tetrakis (isopropylthio)-p-benzoquinone-S2,S3:S5,S 6]] perchlorate acetone solvate, {[Ag(C18H28S4O2)]CIO 4·-C3H6O}n, has been prepared and the molecular structure determined. The silver ion prefers a tetrahedral coordination geometry comprising four S atoms from two different tpq molecules, giving a linear-chain structure of alternating metal cations and organic ligands. Also, the four isopropyl groups of the tpq molecule lie in the perpendicular direction of the plane of the benzoquinone ring.
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