Synthesis p. 955 - 960 (1988)
Update date:2022-08-05
Topics:
Bravo, Pierfrancesco
Frigerio, Massimo
Resnati, Giuseppe
The reduction of some enantiomerically pure perfluoroalkyl α-(p-tolylsulfinyl) ketones was performed.Alcohols containing perfluoroalkyl and p-tolylsulfinyl groups were obtained with high diastereoselection when a phenyl residue was present on the sulfinylated carbon and with lower diastereoselection in the other cases.Removal of the chiral sulfinyl group from single diastereoisomers gave secondary alcohols containing a perfluoroalkyl group in enantiomerically pure form.
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