THE SYNTHESIS OF (-)-SIRENIN, SPERM ATTRACTANT OF THE WATER MOLD ALLOMYCES MACROGYNUS

DOI: 10.1016/S0040-4020(01)86174-3

Source and publish data:

Tetrahedron p. 4713 - 4720 (1988)

Update date:2022-08-04

Topics:

Authors:

Kitahara, Takeshi

Horiguchi, Akira

Mori, Kenji

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Article abstract of DOI:10.1016/S0040-4020(01)86174-3

Synthesis of (-)-sirenin 1a, sperm attracting hormone of Allomyces macrogynus was achieved through 10 steps from (-)-perillaldehyde 3.Formation of cyclopropane ring was executed diastereoselectively by the cyclization via intramolecular epoxide opening under carefully controlled condition.

Full text of DOI:10.1016/S0040-4020(01)86174-3

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