Tetrahedron p. 4713 - 4720 (1988)
Update date:2022-08-04
Topics:
Kitahara, Takeshi
Horiguchi, Akira
Mori, Kenji
Synthesis of (-)-sirenin 1a, sperm attracting hormone of Allomyces macrogynus was achieved through 10 steps from (-)-perillaldehyde 3.Formation of cyclopropane ring was executed diastereoselectively by the cyclization via intramolecular epoxide opening under carefully controlled condition.
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(1989)
