Chemistry Letters p. 633 - 634 (1999)
Update date:2022-09-26
Topics:
Kobiro, Kazuya
Shi, Min
Inoue, Yoshihisa
Multiple introduction of phosphonate groups around the quinone oxygen greatly deforms the p-benzoquinone ring through the steric and electronic repulsion. The repulsion produces not a boat but a chair conformation with a bent angle as large as 17.8°.
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