Journal of Organic Chemistry p. 2726 - 2729 (2010)
Update date:2022-08-03
Topics:
Powell, David A.
Fan, Hope
A room-temperature, copper-catalyzed amination of primary benzylic C?H bonds with primary and secondary sulfonamides is described. The reaction is applicable to the coupling of a range of primary and secondary benzylic hydrocarbons with a diverse set of sulfonamides and is tolerant of substitution on both coupling partners. Factors which influence the selectivity of C?H functionalization between primary and secondary sites are examined.
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Doi:10.1016/j.tet.2010.01.020
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