Competitive Intramolecular Cycloaddition and Tandem Cycloaddition/-Sigmatropic Rearrangement Sequence of Allenyl 3-Vinyl-2-cyclohexenyl Ethers: Evidence for Switching of the Reaction Pathway by the Substituent Effects

DOI: 10.1021/ja00196a041

Source and publish data:

Journal of the American Chemical Society p. 5312 - 5320 (1989)

Update date:2022-08-05

Topics: Substituent Effects

Authors:

Hayakawa, Kenji

Aso, Kazuyoshi

Shiro, Motoo

Kanematsu, Ken

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00196a041

The base-catalyzed intramolecular cycloaddition reactions (t-BuOK, t-BuOH, 83 deg C) of variously substituted propargyl 3-vinyl-2-cyclohexenyl ethers have been investigated.The reaction proceeded smoothly via the initial isomerization to the corresponding

Full text of DOI:10.1021/ja00196a041

Products guided by the article

Product name:2,4-endo-dimethyl-12-oxatricyclo<5.3.1.1^3,11>dodecane-1,7-diene

Cas No:122044-15-9

R&D Labs maybe for 122044-15-9

Jintan City Mego Chemical Co., Ltd

Contact:+86-0519-82814387

Address:23# Dengguan Town, Jintan, Jiangsu Province, China
Zhuhai Rundu Pharmaceutical co.,Ltd

Contact:+86-756-7630755

Address:No.6,North Airport Road,Sanzao Town,Jinwan District
Nanjing Zelang Medical Technology Co. Ltd

Contact:86-25-83063290/13770714480

Address:Ganjiabian 108# 01 Unit,701-702 room,Yao Hua Street,Qixia District,Nanjing,Jiangsu,China
Beijing Mesochem Technology Co.,LTD

website:http://www.mesochem.com

Contact:0086-10-57862036

Address:2301, Floor 23, Building 9 Lippo Plaza, Yard 8 Ronghua Middle Road, ETDZ, Beijing, China
SPRING CHEMICAL INDUSTRY CO.,LTD

Contact:86-187-66672125

Address:linchi industry park.zouping

Relevant to this article

Photoinduced tandem reactions of isoquinoline-1,3,4-trione with alkynes to build Aza-polycycles

Doi:10.1021/jo100218w
(2010)
Radiosynthesis of 4-[¹⁸F]fluoromethyl-L-phenylalanine and [ ¹⁸F]FET via a same strategy and automated synthesis module

Doi:10.1002/jlcr.1701
(2010)
Total synthesis of (-)-aurantioclavine

Doi:10.1021/ol100470g
(2010)
Discovery and structure-activity relationships of 6-(benzoylamino) benzoxaboroles as orally active anti-inflammatory agents

Doi:10.1016/j.bmcl.2013.08.096
(2013)
The antibacterial properties of 6-tuliposide B. Synthesis of 6-tuliposide B analogues and structure-activity relationship

Doi:10.1016/j.phytochem.2009.10.008
(2010)
Sequence specificity of DNA alkylation by the unnatural enantiomer of CC-1065 and its synthetic analogues

Doi:10.1021/ja00168a003
(1990)

Article Doi