A New Route to Functionalised Hydroazulenes. Synthesis of (/-)-Confertin

DOI: 10.1039/c39880001028

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1028 - 1030 (1988)

Update date:2022-09-26

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Authors:

Kennedy, Michael

McKervey, M. Anthony

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Article abstract of DOI:10.1039/c39880001028

The advenced confertin intermediate (13) has been synthesized in 20percent yield from a simple dihydrocinnamic acid precursors, the hydroazulene skeleton having been constructed by rhodium(II) mandelate-catalysed cyclisationring expansion of an α-diazoketone.

Full text of DOI:10.1039/c39880001028

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