Evidence for α-Phosphanyl-α'-sulfinylcarbene to α-Phosphoranyl-α'-sulfanylcarbene Rearrangement. Synthesis of 2-Oxo- and 2-Thioxo-1,2λ5-azaphosphetanes

DOI: 10.1021/jo00279a035

Source and publish data:

Journal of Organic Chemistry p. 4426 - 4430 (1989)

Update date:2022-08-04

Topics: Synthesis Rearrangement

Authors:

Sicard, Ghislaine

Gruetzmacher, Hansjoerg

Baceiredo, Antoine

Ficher, Jean

Bertrand, Guy

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Article abstract of DOI:10.1021/jo00279a035

(trimethylsilyl)diazomethane (1) reacts with p-toluenesulfinyl chloride and p-toluenesulfonyl chloride, affording the same 2-oxo-1,2λ⁵-azaphosphetane 6 in 85 and 80percent yield, respectively.These results are r

Full text of DOI:10.1021/jo00279a035

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Product name:Diisopropyl-(1-isopropyl-4,4-dimethyl-2-oxo-3-p-tolylsulfanyl-2λ⁵-[1,2]azaphosphetidin-2-yl)-amine

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