Evidence for α-Phosphanyl-α'-sulfinylcarbene to α-Phosphoranyl-α'-sulfanylcarbene Rearrangement. Synthesis of 2-Oxo- and 2-Thioxo-1,2λ5-azaphosphetanes

DOI: 10.1021/jo00279a035

Source and publish data:

Journal of Organic Chemistry p. 4426 - 4430 (1989)

Update date:2022-08-04

Topics: Synthesis Rearrangement

Authors:

Sicard, Ghislaine

Gruetzmacher, Hansjoerg

Baceiredo, Antoine

Ficher, Jean

Bertrand, Guy

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00279a035

(trimethylsilyl)diazomethane (1) reacts with p-toluenesulfinyl chloride and p-toluenesulfonyl chloride, affording the same 2-oxo-1,2λ⁵-azaphosphetane 6 in 85 and 80percent yield, respectively.These results are r

Full text of DOI:10.1021/jo00279a035

Products guided by the article

Product name:Diisopropyl-(1-isopropyl-4,4-dimethyl-2-oxo-3-p-tolylsulfanyl-2λ⁵-[1,2]azaphosphetidin-2-yl)-amine

Cas No:122093-54-3

R&D Labs maybe for 122093-54-3

Anhui Asahikasei Chemical Co., Ltd

Contact:86-551-4259770

Address:No. 88 Linquan Road Hefei Anhui China
enantiotech corporation ltd

Contact:+86-0760-85282375

Address:zhongjing road,zhongshan torch hi-tech industrial development zone
Yingkou Sanzheng New Technology Chemical Industry Co., Ltd.

Contact:+86-417-2927806

Address:yingkou
A-Chem Technologies Co.,Ltd.

Contact:+86-512-69561895

Address:No.111, Building A4, 218 Xinghu Street, Suzhou Industrial Park, P. R. China
Hangzhou Yingshanhua Pigment Chemicals Co.,Ltd.

Contact:+86-0150-58101658

Address:Nanyang Economic DevelopmentZong,Xiaoshan,Hangzhou,China

Relevant to this article

Dehydrogenative and decarboxylative C-H alkynylation of heteroarenes catalyzed by Pd(II)-carbene complex

Doi:10.1016/j.tet.2015.02.020
(2015)
Antioxidant and antiviral activities of silybin fatty acid conjugates

Doi:10.1016/j.ejmech.2009.11.056
(2010)
Chemoselective glycosylations using 2,3-unsaturated-4-keto glycosyl donors

Doi:10.1039/b925587g
(2010)
Nickel(ii) and iron(iii) selective off-on-type fluorescence probes based on perylene tetracarboxylic diimide

Doi:10.1039/b921342b
(2010)
Synthesis, crystal structures, and superoxide dismutase activity of two isostructural copper(II)-zinc(II) complexes derived from N,N′-bis(4-methoxysalicylidene) cyclohexane-1,2-diamine

Doi:10.1080/00958970903515134
(2010)
Thiosemicarbazones, semicarbazones, dithiocarbazates and hydrazide/hydrazones: Anti - Mycobacterium tuberculosis activity and cytotoxicity

Doi:10.1016/j.ejmech.2010.01.028
(2010)

Article Doi