Erratum: Rhodium(III)-catalyzed isoquinolone synthesis: The N-O bond as a handle for C-N bond formation and catalyst turnover (Journal of the American Chemical Society (2010) 132 (6908-6909))

Full text of DOI:10.1021/ja3096625

Addition/Correction
pubs.acs.org/JACS
Correction to Rhodium(III)-Catalyzed Isoquinolone Synthesis: The
N−O Bond as a Handle for C−N Bond Formation and Catalyst
Turnover
Nicolas Guimond,* Christina Gouliaras, and Keith Fagnou
J. Am. Chem. Soc. 2010, 132, 6908−6909. DOI: 10.1021/ja102571b
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* Supporting Information
Following a recent report from Huang et al.,1 we further
investigated the structure of 3a. In accordance with the
proposed structure in Huang’s report, X-ray crystallographic
analysis confirmed that 3a is not an isoquinolone but rather the
heterocycle resulting from C−O bond reductive elimination
(see structure below). This correction does not alter the
outcome of our work as it is focused on the synthesis of
isoquinolones where the N−O bond has undergone cleavage.
The Supporting Information was modified to match the
correct structure of 3a. An electronic crystallographic
information file (CIF) was also made available.
ASSOCIATED CONTENT
* Supporting Information
Detailed experimental procedures and characterization data for
all new compounds. This material is available free of charge via
the Internet at http://pubs.acs.org
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REFERENCES
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(1) Zhong, H.; Yang, D.; Wang, S.; Huang, J. Chem. Commun. 2012,
48, 3236.
Published: October 22, 2012
© 2012 American Chemical Society
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dx.doi.org/10.1021/ja3096625 | J. Am. Chem. Soc. 2012, 134, 18148−18148