Reactions of Stable 2-olefin)(α-di-imine)> Complexes. Retention of the Five-co-ordinate Structure upon Halogen Exchange and Ligand Substitution with Olefins, α-Di-imines, and N,N'-Disubstituted 1,2-Diaminoethanes

DOI: 10.1039/DT9810002164

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2164 - 2171 (1981)

Update date:2022-07-31

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Authors:

Poel, Henk van der

Koten, Gerard van

Stein, Gerard C. van

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Article abstract of DOI:10.1039/DT9810002164

The axial halogen atoms as well as the equatorial ν²-C2H4 and ?,?-N,N' chelate-bonded R-N=CH-CH=N-R or R-N(H)CH2CH2N(H)-R ligands (L-L) in five-co-ordinate 2-C2H4)(?,?-N,N'-L-L)> can be replaced with retention of the trigonal

Full text of DOI:10.1039/DT9810002164

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