
Synthesis p. 185 - 191 (1992)
Update date:2022-08-02
Topics: Migration Epoxidation Stereocontrolled Synthesis Diene Vinyl group Anionic oxy-Cope rearrangement
Ladouceur
Paquette
Methodology is described for expedient synthesis of the A/B framework of 8,9-seco-ent-kaurenes and for introduction of the 5-methylene-2-cyclopentenone moiety. In the first part of the study, a sequence of only six steps is necessary to convert 2-(hydroxy
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(1999)Doi:10.3987/COM-09-11890
(2010)Doi:10.1021/ja1012917
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(2009)Doi:10.1039/d0md00074d
(2020)