Mechanistic Impact of Oxime Formation Accompanying 1,3-Dipolar Cycloadditions of Nitrile Oxides

DOI: 10.1021/jo00282a012

Source and publish data:

Journal of Organic Chemistry p. 5012 - 5016 (1989)

Update date:2022-07-31

Topics: Oxime 1,3-Dipolar Cycloadditions Nitrile oxides

Authors:

Baran, Janusz

Mayr, Herbert

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Article abstract of DOI:10.1021/jo00282a012

Benzonitrile oxide (1a) reacts with 1,1,2,2,3,3-hexamethyl-4,5-bis(methylene)cyclopentane (5) to give a mixture of the 1,3-dipolar cycloaddition product 8 and the oxime 9.This reaction is 26 times slower than the corresponding reaction of 1a with 1,2-bis(

Full text of DOI:10.1021/jo00282a012

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