AMINE-DIRECTED LITHIATION IN ALIPHATIC ORGANOPHOSPHORUS SYSTEMS. AN APPROACH TO α-MONOALKYLATION OF α,β-UNSATURATED PHOSPHINE OXIDES

DOI: 10.1016/S0040-4039(00)95233-X

Source and publish data:

Tetrahedron Letters p. 477 - 480 (1989)

Update date:2022-09-26

Topics: Amine Selective Chemical Reaction Approach Position Aliphatic α,β-Unsaturated Organophosphorus Phosphine oxide Directed Lithiation

Authors:

Pietrusiewicz, K. Michal

Zablocka, Maria

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Article abstract of DOI:10.1016/S0040-4039(00)95233-X

Novel optically active α,β-unsaturated phosphine oxides are prepared in one pot via regioselective alkylation of amine protected homochiral vinyl phosphine oxides.

Full text of DOI:10.1016/S0040-4039(00)95233-X

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Product name:Dimethyl-[(R)-2-((S)-methyl-phenyl-phosphinoyl)-3-phenyl-propyl]-amine

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