X=Y-ZH SYSTEMS AS POTENTIAL 1,3-DIPOLES. PART 22. CYCLOADDITION REACTIONS OF PYRIDOXAL IMINES. RELEVANCE TO α-AMINO ACID RACEMASES AND TRANSAMINASES.

DOI: 10.1016/S0040-4020(01)86100-7

Source and publish data:

Tetrahedron p. 7283 - 7292 (1988)

Update date:2022-07-29

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Authors:

Grigg, Ronald

Thianpatanagul, Sunit

Kemp, James

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Article abstract of DOI:10.1016/S0040-4020(01)86100-7

Pyridoxal imines of α-amino acid esters and related amines undergo cycloaddition to N-phenylmaleimide on heating in acetonitrile, toluene or xylene.The cycloadditions proceed in good yield, are stereospecific, and involve an endo-transition state.The reac

Full text of DOI:10.1016/S0040-4020(01)86100-7

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