Tetrahedron Letters p. 2353 - 2356 (1988)
Update date:2022-07-29
Topics:
Kocienski, Philip
Dixon, Nicholas J.
Wadman, Sjoerd
The nickel-catalysed coupling of certain Grignard reagents with 6-alkyl-3,4-dihydro-2H-pyrans is highly stereoselective and gives tri-substituted alkenes with retention of configuration.The method was applied to the synthesis of (E)-3-Acetoxy-7-methyl-6-nonene, the aggregation pheromone of the square-necked grain beetle.
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