Journal of Organic Chemistry p. 5539 - 5543 (1989)
Update date:2022-08-05
Topics:
Inghardt, Tord
Frejd, Torbjoern
Benzyl 2-deoxy-2-C-methylpentopyranosides ring open via attack at the anomeric carbon by the nucleophilic part of organoaluminum reagents (Me2AlR) to give chiral, partially protected, branched 1,2,3,5-tetrol derivatives 13-32.The reaction represents a direct chain extension of the glycosides at C-1.
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