Different Structural Features of Half-sandwich Complexes of Rhodium(I) containing the η5-1,2,4-Triphosphacyclopentadienyl Ring. Syntheses and (31)P N.M.R. Spectra of 5-C2R2P3)LL'> t, L = L'= PPh3P(p-tolyl)3; L

DOI: 10.1039/c39880001475

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Journal of the Chemical Society. Chemical communications p. 1475 - 1476 (1988)

Update date:2022-09-26

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Authors:

Bartsch, Rainer

Hitchcock, Peter B.

Madden, Timothy J.

Meidine, Mohamed F.

Nixon, John F.

Wang, Hongrui

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Article abstract of DOI:10.1039/c39880001475

First examples of η⁵-1,2,4-triphosphacyclopentadienyl complexes of rhodium are reported and their structures, elucidated by (31)P n.m.r. spectroscopy and X-ray diffraction studies, show interesting differences.

Full text of DOI:10.1039/c39880001475

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