Tetrahedron Letters p. 4811 - 4814 (1988)
Update date:2022-08-04
Topics:
Marshall, James A.
Markwalder, Jay A.
The homochiral epoxy stannane aldehyde 13 affords a 2.3:1 mixture of cis-Z and cis-E cyclization products 14 and 15 upon treatment with BF3*Et2O at -78 deg C whereas the diastereomeric epoxy stannane aldehyde 16 gives the cis-Z product 17 with only a trace of the cis-E isomer 18.
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