SOLVOLYTIC REACTIVITY OF 1-(1-METHYL-2-PYRROLYL)-2,2,2-TRIFLUOROETHYL p-NITROBENZOATE

DOI: 10.1016/S0040-4039(00)99454-1

Source and publish data:

Tetrahedron Letters p. 1319 - 1322 (1989)

Update date:2022-08-02

Topics:

Authors:

Kwong-Chip, Jean-Marc

Tidwell, Thomas T.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)99454-1

1-(1-Methyl-2-pyrrolyl)-2,2,2-trifluoroethyl p-nitrobenzoate (1) solvolyses to form a carbocation intermediate 4 as evidenced by the dependence on the solvent ionizing power Y_OTs and the formation of substitution products.The rate ratio k(H)/k(CF₃) of only 40 indicates strong electron donation to the destabilized carbocation.

Full text of DOI:10.1016/S0040-4039(00)99454-1

Products guided by the article

Product name:1-(1-methyl-2-pyrrolyl)-2,2,2-trifluoroethyl p-nitrobenzoate

Cas No:123136-34-5

R&D Labs maybe for 123136-34-5

Shijiazhuang City Xiehe Pharmaceutical Co., Ltd

Contact:+86-311-80817929

Address:Shangzhuang,Shijiazhuang,China
Shanghai Bocimed Pharmaceutical Co., Ltd.

website:http://www.bocimed.com

Contact:+86-21-68861632

Address:Building 1, Lane 647, Songtao Road, Zhangjiang High-Tech Park, Shanghai
ChangZhou XiaQing Chemical Co., Ltd.

Contact:+86-519-88721665

Address:3# Hengluo Road, Henglin Town, Changzhou City, Jiangsu Province，China
Shanghai Mio Chemical Co., Ltd

Contact:0086 21- 64401188-622

Address:16 Floor NO.2 Jiefang Building, No. 4855 Dushi Road, 201100 Shanghai, P.R.China
Suzhou SuKaiLu Chemical Technology Co., Ltd.

Contact:+86-512-62766020

Address:Floor 4, Building 1, Xinyi Pharmaceutical Valley Wisdom Industrial Park, 415 Changyang Street, Suzhou Industrial Park, Jiangsu Province

Relevant to this article

A new reaction of 1,2-di- and 1,2,3-trialkyldiaziridines: Ring expansion under the action of diethyl acetylenedicarboxylate in ionic liquids

Doi:10.1002/jhet.204
(2009)
Doi:10.1021/ja01600a063
(1956)
Synthesis of uridine 5'-(2-acetamido-2,4-dideoxy-4-fluoro-alpha-D-galactopyranosyl) diphosphate and uridine 5'-(2-acetamido-2,6-dideoxy-6-fluoro-alpha-D-glucopyranosyl) diphosphate.

Doi:10.1016/0008-6215(88)80007-7
(1988)
Nano-ZnO: An efficient and reusable catalyst for one-pot synthesis of 1H-pyrazolo[1,2-b]phthalazine-5,10-diones and pyrazolo[1,2-a][1,2,4]triazole-1, 3-diones

Doi:10.1007/s13738-012-0159-3
(2013)
Electric-Field-Mediated Electron Tunneling of Supramolecular Naphthalimide Nanostructures for Biomimetic H₂ Production

Doi:10.1002/anie.202009267
(2021)
Tandem reactions of 6-phenylethynylpyrimidine-5-carbaldehydes with alcohols: regioselective synthesis of 5-alkoxy-(7Z)-7-benzylidene-5,7-dihydrofuro[3,4-d]pyrimidines and 5-alkoxy-7-phenyl-5H-pyrano[4,3-d]pyrimidines

Doi:10.1016/j.tet.2009.10.108
(2010)

Article Doi