The First Rhenium Oxo-Alkylidene Complex. X-Ray Structure of ReO2(CH2CMe3)

DOI: 10.1039/c39880001489

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1489 - 1490 (1988)

Update date:2022-08-04

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Authors:

Cai, Shiang

Hoffman, David M.

Wierda, Derk A.

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Article abstract of DOI:10.1039/c39880001489

Ohotolysis of ReO2(CH2CMe3)3 in pyridine gives the alkylidene complex ReO2(CH2CMe3) in 76percent yield; an X-ray crystallographic study shows ReO2(CH2CMe3) has a distorted tetrahedral structure.

Full text of DOI:10.1039/c39880001489

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