TRANSANNULAR BOND FORMATION BETWEEN THE ANTIMONY AND THE NITROGEN ATOMS IN DIBENZAZASTIBOCINE SYSTEM. FORMATION OF X-Sb-X AND X-Sb-N(1+) HYPERVALENT BOND

DOI: 10.1016/S0040-4039(00)82879-8

Source and publish data:

Tetrahedron Letters p. 5401 - 5404 (1988)

Update date:2022-08-04

Topics:

Authors:

Ohkata, Katsuo

Ohnishi, Masako

Akiba, Kin-ya

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Article abstract of DOI:10.1016/S0040-4039(00)82879-8

6-Methyl-5,6,7,12-tetrahydro-12-p-tolyldibenz<1,5>azastibocine (1) was prepared by means of one-pot reaction of di(o-bromobenzyl)methylamine (2), butyllithium, and antimony trichloride, followed by p-tolyllithium in 23percent yield.Halogenation of 1

Full text of DOI:10.1016/S0040-4039(00)82879-8

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