Reaction of pummerer rearrangement intermediate with thiols: New synthetic method of S,S-thioacetals of formylphosphonate

Article abstract of DOI:10.1080/00397919408019056

Pummerer rearrangement reaction intermediate(2) of phenylsulfinyl methanephosphonate(1) has been found to react mildly with thiols(3) in the presence of stannic chloride to provide S,S-thioacetals of formylphosphonate(4).

Full text of DOI:10.1080/00397919408019056

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Synthetic Communications: An
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Reaction of Pummerer
Rearrangement Intermediate
with Thiols: New Synthetic
Method of S,S-Thioacetals of
Formylphosphonate
Taek Hyeon Kim a & Dong Young Oh b
a Department of Fine Chemical Technology ,
Chonnam National University , Kwangju, 500-757,
Korea
b Department of Chemistry , Korea Advanced
Institute of Science and Technology , Taejeon,
305-701, Korea
Published online: 23 Sep 2006.
To cite this article: Taek Hyeon Kim & Dong Young Oh (1994) Reaction of Pummerer
Rearrangement Intermediate with Thiols: New Synthetic Method of S,S-Thioacetals
of Formylphosphonate, Synthetic Communications: An International Journal for
Rapid Communication of Synthetic Organic Chemistry, 24:16, 2313-2318, DOI:
10.1080/00397919408019056
To link to this article: http://dx.doi.org/10.1080/00397919408019056
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