Cleavage of Isoxazolines with Tricarbonyltris(acetonitrile)molybdenum and Silica Gel. Synthesis of 1-(2-Oxoalkyl)cyclopropanols from Isoxazoline-5-spirocyclopropanes

DOI: 10.1055/s-1989-27185

Source and publish data:

Synthesis p. 175 - 178 (1989)

Update date:2022-08-03

Topics:

Authors:

Guarna, Antonio

Guidi, Antonio

Goti, Andrea

Brandi, Alberto

Sarlo, Francesco De

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1989-27185

An efficient synthesis of 1-(2-oxoalkyl)cyclopropanols from isoxazoline-5-spirocyclopropanes by selective N-O cleavage effected by Mo(CO)3(MeCN)3 and silica gel is described.

Full text of DOI:10.1055/s-1989-27185

Products guided by the article

Product name:2-(7-Hydroxy-bicyclo[4.1.0]hept-7-yl)-1-phenyl-ethanone

Cas No:123433-73-8

R&D Labs maybe for 123433-73-8

Shandong LuZhou Amino Acid Co., Ltd

Contact:86-539-2218025

Address:yishui economic and technical development zone zhenxing south road
Nanjing Capatue Chemical Co., Ltd

Contact:+86-25-86371192 +86-025-85720158

Address:No.20 Jiangjun Avenue, Jiangning Economic & Technical Development Zone
Shanghai TBBMed Co.,Ltd

website:http://www.tbbmed.com

Contact:86--21-50498136

Address:Room 6002, Building 7-1, No.160 Basheng Road,Pudong Area,Shanghai China
Neworld Chemical Co., Ltd Shanghai(expird)

Contact:+86-21-62202658

Address:11F, Blvd 2, No. 1969 PuXing Rd, Shanghai
Chengdu Sino-Strong Pharmaceutical Co.,Ltd.

website:http://www.sino-strong.com.cn

Contact:+86-28-82666753

Address:459 West haike road,Cross-straits technological industry park, Wenjiang district,Chengdu, P.R.China

Relevant to this article

Synthesis of new bulky isocyanide ligands and their use for Rh-catalyzed hydrosilylation

Doi:10.1246/cl.2006.1038
(2006)
A comparative repair study of thymine- and uracil-photodimers with model compounds and a photolyase repair enzyme

Doi:10.1002/(SICI)1521-3765(20000103)6:1<62::AID-CHEM62>3.0.CO;2-7
(2000)
Cycloaddition of Anhydro-3-hydroxy-2-phenylthiazolo<3,2-c>quinazolin-4-ium Hydroxide with Olefinic Dipolarophiles

Doi:10.1039/c39840000213
(1984)
Highly Diastereo- and Enantioselective Synthesis of α-Spiro-δ-lactams by an Organocascade Reaction

Doi:10.1002/ejoc.201700193
(2017)
α-Aminoxy-Acid-Auxiliary-Enabled Intermolecular Radical γ-C(sp³)?H Functionalization of Ketones

Doi:10.1002/anie.201712066
(2018)
Synthesis, structure of borylmagnesium, and its reaction with benzaldehyde to form benzoylborane

Doi:10.1021/ja073037t
(2007)

Article Doi