A NOVEL SYNTHESIS OF 1,1-DIFLUOROOLEFINS FROM 1,1,1-TRIFLUOROETHYL p-TOLUENESULFONATE VIA BORONATE-COMPLEX

DOI: 10.1016/S0040-4039(00)99541-8

Source and publish data:

Tetrahedron Letters p. 1641 - 1644 (1989)

Update date:2022-07-31

Topics:

Authors:

Ichikawa, Junji

Sonoda, Takaaki

Kobayashi, Hiroshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)99541-8

The nucleophilic substitution of gem-difluorovinylic tosyloxy group with alkyl groups is effected by treating 2,2-difluoro-1-tosyloxyvinyllithium with trialkylboranes to afford 1,1-difluoroolefins in good yields.

Full text of DOI:10.1016/S0040-4039(00)99541-8

Products guided by the article

Product name:Bicyclo[2.2.1]heptane, 2-(2,2-difluoroethenyl)-

Cas No:123455-94-7

R&D Labs maybe for 123455-94-7

suzhou chukai pharmateach co,.ltd

Contact:86-512-88812511

Address:Building 3, Wujiang Scientific Innovation Park, 2358 Changan Rd, Wujiang 215200, Jiangsu Province, P. R. China
Wuhan HengHeDa Pharm Co., Ltd

Contact:86-27-84888681

Address:Wuhan economic & technology development zone
Zhenjiang Huayu I/E Co.,LTD

Contact:86-511-85210668 0511-85210668, 85210818, 85210898

Address:Yihai Garden E-902,NO.99 Daxi RD., Zhenjiang Jiiangsu ,China
Changzhou BaoKang Pharmaceutical & Chemical Co., Ltd

Contact:(86) 519-88782201 88784080 88785278

Address:Henglin town, changzhou,Jiangsu
Tengzhou Runlong Fragrance Co., Ltd.

website:http://www.tzrunlong.com/

Contact:--

Address:No. 78, Fushan Road, Biomedical Industrial Park, Dawu Town, Tengzhou, Shandong, 277514 China

Relevant to this article

Synthesis of heteroleptic iron(II) 2-pyridylmethylamides and 2-pyridylmethylideneamines via the reaction of [(thf)Fe{N(SiMe₃) ₂}₂Cl] with (2-pyridylmethyl)(trialkylsilyl)amines

Doi:10.1039/b926723a
(2010)
Reactions of aromatic heterocycles with uranium alkyl complexes

Doi:10.1021/ic1009835
(2010)
Stereoselective cross-coupling of baylis-hillman acetates with diphenyl disulfides and diselenides using palladium acetate

Doi:10.1080/00397910903219468
(2010)
Isomerization of an N-heterocyclic germylene to an azagermabenzen-1-ylidene and its coupling to a unique bis(germylene)

Doi:10.1021/om100383y
(2010)
CONVENIENT KETONE SYNTHESIS VIA N-ACYLAZIRIDINES

Doi:10.1016/S0040-4039(01)80033-2
(1984)
Semi-synthesis of dihydrochalcone derivatives and their in vitro antimicrobial activities

Doi:10.1055/s-0029-1240619
(2010)

Article Doi