SYNTHESIS OF MACROCYCLIC TERPENOIDS BY INTRAMOLECULAR CYCLIZATION XIII. STEREOSELECTIVE SYNTHESIS OF (+/-) CUBITENE, A COMPONENT OF DEFENSE SECRETION OF TERMITES

DOI: 10.1016/S0040-4020(01)86074-9

Source and publish data:

Tetrahedron p. 7055 - 7062 (1988)

Update date:2022-08-02

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Authors:

Kodama, Mitsuaki

Takahashi, Toshiya

Kojima, Tsutomu

Ito, Sho

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Article abstract of DOI:10.1016/S0040-4020(01)86074-9

Stereoselective synthesis of cubitene (1), a novel diterpene isolated from defense secretion of termites, has been accomplished using an intramolecular reaction of α-sulfenyl carbanion with epoxide.Hydride reduction of the ketone 11 obtained by Claisen re

Full text of DOI:10.1016/S0040-4020(01)86074-9

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