TOTAL SYNTHESIS OF (+)-METHYL TRISPORATE B, FUNGAL SEX HORMONE

DOI: 10.1016/S0040-4020(01)86076-2

Source and publish data:

Tetrahedron p. 7081 - 7088 (1988)

Update date:2022-08-04

Topics:

Authors:

Takahashi, Shunya

Oritani, Takayuki

Yamashita, Kyohei

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Article abstract of DOI:10.1016/S0040-4020(01)86076-2

The enantioselective synthesis of (+)-methyl trisporates B (2 and 4) has been described.The chiral enedione 11, which was prepared by asymetric aldol condensation of the prochiral triketone 12, was converted to α-hydroxyketone 9 via the oxobenzoate 10.Cle

Full text of DOI:10.1016/S0040-4020(01)86076-2

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