REGIOSELECTION IN THE HYDROFORMYLATION OF t-BUTYLDIPHENYLSILYLALKENES: A NEW APPROACH TO ALDOL SYNTHESIS

DOI: 10.1016/S0040-4039(00)95168-2

Source and publish data:

Tetrahedron Letters p. 233 - 234 (1989)

Update date:2022-08-16

Topics: Hydroformylation

Authors:

Doyle, M. Michael

Jackson, W. Roy

Perlmutter, Patrick

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Article abstract of DOI:10.1016/S0040-4039(00)95168-2

Hydroformylation of (Z)-alkenes bearing a t-butyldiphenylsilyl group (TBDPS) yields, almost exclusively, β-silylaldehydes and the methodology has been used to establish a new aldol synthesis.

Full text of DOI:10.1016/S0040-4039(00)95168-2

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Product name:tert-Butyl-((Z)-3-methoxy-allyl)-diphenyl-silane

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