Journal of the American Chemical Society p. 9203 - 9205 (1989)
Update date:2022-07-29
Topics:
Kraus
Thurston
A 10-step synthesis of hydroxysemperoside deglucoside has been achieved. The key step is an organopalladium-mediated cyclization that produces a highly functionalized oxabicyclooctane. The remaining functional groups are introduced by addition to the exo face of the fused bicyclic system.
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