SYNTHESIS OF RIGIDLY LINKED TRIAD MOLECULES BASED ON OCTAALKYLPORPHYRIN, CAPABLE OF MULTISTEP ELECTRON TRANSFER

DOI: 10.1007/BF01165028

Source and publish data:

Chemistry of Heterocyclic Compounds p. 905 - 915 (1994)

Update date:2022-08-03

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Authors:

Gribkov, A.A.

Borovkov, V.V.

Evstigneeva, R.P.

Sakata, Y.

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Article abstract of DOI:10.1007/BF01165028

We have designed and carried out the synthesis of triad model systems containing octaalkylporphyrin, benzoquinone, and trichlorobenzoquinone with an oxidation-reduction potential gradient in the molecule.The quinone moieties are fixed relative to the porphyrin using spiro<4,4>nonane and methylene spacers.

Full text of DOI:10.1007/BF01165028

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