Carbene-complex-promoted Ring Expansion of Aziridine: Formation of the 1-Azabicyclo Ring System by a Double Alkyne and a Single Carbon Monoxide Insertion Reaction

DOI: 10.1039/c39880001303

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1303 - 1305 (1988)

Update date:2022-08-03

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Authors:

Denise, Bernard

Parlier, Andrei

Rudler, Henri

Vaissermann, Jacqueline

Daran, J. C.

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Article abstract of DOI:10.1039/c39880001303

A chromium carbene complex (2) bearing a 2-methylaziridine ring system on the carbene carbon atom easily undergoes a double diphenylacetylene and a single CO insertion reaction to give a 1-oxotetrahydroindolizine derivative (4), which has been fully characterized by X-ray analysis of its Cr(CO)3 adduct (3).

Full text of DOI:10.1039/c39880001303

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