Carbene-complex-promoted Ring Expansion of Aziridine: Formation of the 1-Azabicyclo Ring System by a Double Alkyne and a Single Carbon Monoxide Insertion Reaction

DOI: 10.1039/c39880001303

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1303 - 1305 (1988)

Update date:2022-08-03

Topics:

Authors:

Denise, Bernard

Parlier, Andrei

Rudler, Henri

Vaissermann, Jacqueline

Daran, J. C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39880001303

A chromium carbene complex (2) bearing a 2-methylaziridine ring system on the carbene carbon atom easily undergoes a double diphenylacetylene and a single CO insertion reaction to give a 1-oxotetrahydroindolizine derivative (4), which has been fully characterized by X-ray analysis of its Cr(CO)3 adduct (3).

Full text of DOI:10.1039/c39880001303

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Cr(CO)3(C₈H₃N(O)(C₆H₅)4(CH₃)2)

Cas No:123931-45-3

R&D Labs maybe for 123931-45-3

Foreschem Co., Ltd

Contact:+86-533-3112891

Address:zibo
SHANXI XINTIANYUAN PHARMACEUTICAL CO., LTD.

website:http://www.tychemical.com

Contact:0086-358-3521713 3521715

Address:No. 1 Yintong Road, Shanxi Jiaocheng Economic Development Zone, Xiajiaying Town, Jiaocheng County, Lvliang City, Shanxi Province, China
changsha chenjin chemical technology co.,LtD(expird)

Contact:86-731-84451263

Address:Room 201/217-218, 101 Jingyuan Electronic Technology Co.,Ltd. Testing Center, No.69, Lufeng Road, High-tech Development Zone, Changsha, China
Chongqing Werlchem Fine Chemical Co. Ltd

Contact:+86-23-67521957

Address:NO.15,Fortune Road,Yubei District,401121,Chongqing,China
Hawks Chemical

Contact:+44 (0)161 367 9441

Address:

Relevant to this article

Efficient 2-aryl benzothiazole formation from acetophenones, anilines, and elemental sulfur by iodine-catalyzed oxidative C(CO)-C(alkyl) bond cleavage

Doi:10.1016/j.tet.2018.08.047
(2018)
Fast isomerizing methyl iodide azopyridinium salts for molecular switches

Doi:10.1021/ol1013679
(2010)
Substituent effect on the stereoselectivity of acylation of racemic heterocyclic amines with N-phthaloyl-3-aryl-(S)-alanyl chlorides

Doi:10.1016/j.tetasy.2010.12.017
(2011)
Asymmetric alkyl-alkyl cross-couplings of unactivated secondary alkyl electrophiles: Stereoconvergent suzuki reactions of racemic acylated halohydrins

Doi:10.1021/ja105924f
(2010)
A FACILE SYNTHESIS OF 3-ARYL-4-HYDROXYCOUMARINS

Doi:10.1016/S0040-4039(00)99513-3
(1989)
Regio- and stereocontrolled functionalization of a seven-membered ring via (cycloheptatriene)iron tricarbonyl

Doi:10.1021/ja00157a033
(1990)

Article Doi