Regio- and stereocontrolled functionalization of a seven-membered ring via (cycloheptatriene)iron tricarbonyl

DOI: 10.1021/ja00157a033

Source and publish data:

Journal of the American Chemical Society p. 205 - 215 (1990)

Update date:2022-08-03

Topics:

Authors:

Williams

Rudisill

Barnum Barnum

Hardcastle

He yn He yn

Kozak Kozak

McMillan

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Article abstract of DOI:10.1021/ja00157a033

Deprotonation of (cycloheptatriene)Fe(CO)₃ gives a deep red nucleophilic anion (C₇H₇)Fe(CO)₃(K⁺), 1. Anion 1 reacts with acid chlorides to give (7-exo-acyl-C₇H₇)Fe (CO)_{3
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Full text of DOI:10.1021/ja00157a033

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Product name:E-{1-4-η-8-phenyl-8-n-propoxyheptafulvene}iron tricarbonyl

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