Tetrahedron p. 3889 - 3896 (1989)
Update date:2022-08-02
Topics:
Vonk, C.R.
Davelaar, E.
Ribot, S.A.
Phosphitylation of the allylic hydroxy group in 9-tetrahydropyranyl trans-zeatine with salicyl chlorophosphite gives the allyl phosphonate monoester 5, which can be readily converted into the corresponding phosphate 7, methylphosphate 8 or thiophosphate 9.After cleavage of the tetrahydropyranyl group under mild acidic condition allylic phosphate derivatives of trans-zeatin are obtained.
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