Acid-base organocatalysts for the aza-Morita-Baylis-Hillman reaction of nitroalkenes

DOI: 10.1016/j.tetasy.2010.05.027

Source and publish data:

Tetrahedron Asymmetry p. 891 - 894 (2010)

Update date:2022-09-26

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Authors:

Takizawa, Shinobu

Horii, Atsushi

Sasai, Hiroaki

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Article abstract of DOI:10.1016/j.tetasy.2010.05.027

A new class of acid-base chiral organocatalysts 1a and 2 for aza-Morita-Baylis-Hillman (aza-MBH) reaction of conjugated nitroalkenes is described. The acidic phenolic hydroxy groups and basic imidazole unit cooperatively activate nitroalkenes to promote the aza-MBH reaction in good yields with moderate enantioselectivities.

Full text of DOI:10.1016/j.tetasy.2010.05.027

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