6-Thia-1-aza-5λ5-phosphabicyclohept-3-enes and Isothiocyanatophosphine-sulfides from (Methylidenamino)phosphines, Carbon Disulfide, and Acetylene- or Ethylene Derivatives

DOI: 10.1002/hlca.19890720118

Source and publish data:

Helvetica Chimica Acta p. 139 - 146 (1989)

Update date:2022-09-26

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Authors:

Fulde, Maria von

Ried, Walter

Bats, Jan W.

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Article abstract of DOI:10.1002/hlca.19890720118

(Methylidenamino)phosphines react with carbon disulfide to 1,3,2-thiazaphosphete derivatives 2.Acetylenedicarboxylates give with 2 6-thia-1-aza-5λ⁵-phosphabicyclo<3.2.0>hept-3-enes 4a, b, and acrylates yield isothiocyanatophosphin-sulfides 5a-c

Full text of DOI:10.1002/hlca.19890720118

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