The Conversion of Acyl Silanes into Chiral Secondary Alcohols

DOI: 10.1039/c39890000089

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 89 - 90 (1989)

Update date:2022-07-30

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Authors:

Buynak, John D.

Strickland, J. Byron

Hurd, Trace

Phan, Andrew

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Article abstract of DOI:10.1039/c39890000089

Chiral secondary carbinols are prepared in high enantiomeric excess by a new process involving the reduction of acyl silanes and utilising a thermal rearrangement of α-acetoxy silanes.

Full text of DOI:10.1039/c39890000089

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