Synthesis of Polypropionate Subunits by SN2'Addition of Cuprates to Nonracemic Acyclic Vinyloxiranes

DOI: 10.1021/jo00292a031

Source and publish data:

Journal of Organic Chemistry p. 1540 - 1547 (1990)

Update date:2022-08-04

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Authors:

Marshall, James A.

Blough, Bruce E.

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Article abstract of DOI:10.1021/jo00292a031

Synthetic sequences have been devised for conversion of the chiral pool ester 1 to differentially protected polypropionate subunit polyols 11, 13, 18, and 20.The following stereochemically significant steps were employed: (1) reagent directed Sharpless ep

Full text of DOI:10.1021/jo00292a031

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