Tetrahedron Letters p. 2783 - 2786 (1989)
Update date:2022-08-03
Topics: Asymmetric synthesis Chiral Phosphine Oxides Experimental terms Phosphines Phosphinates Michaelis-Arbuzov rearrangement Oxazaphospholidine
Juge, S.
Genet, J. P.
A general approach to asymmetric synthesis of high optically active tertiary organophosphorus compounds is described.Oxazaphospholidine 3 reacts with alkyl halide to give regio and stereoselectively the corresponding phosphinamide 4.Methyl phenyl phosphin
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