Asymmetric synthesis of phosphinates, phosphine oxides and phosphines by Michaelis Arbuzov rearrangement of chiral oxazaphospholidine

DOI: 10.1016/S0040-4039(00)99124-X

Source and publish data:

Tetrahedron Letters p. 2783 - 2786 (1989)

Update date:2022-08-03

Topics: Asymmetric synthesis Chiral Phosphine Oxides Experimental terms Phosphines Phosphinates

Authors:

Juge, S.

Genet, J. P.

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Article abstract of DOI:10.1016/S0040-4039(00)99124-X

A general approach to asymmetric synthesis of high optically active tertiary organophosphorus compounds is described.Oxazaphospholidine 3 reacts with alkyl halide to give regio and stereoselectively the corresponding phosphinamide 4.Methyl phenyl phosphin

Full text of DOI:10.1016/S0040-4039(00)99124-X

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