An expeditious synthesis of (3S,4S)-statine and (3S,4S)cyclohexylstatine

DOI: 10.1016/S0040-4039(00)94374-0

Source and publish data:

Tetrahedron Letters p. 217 - 218 (1990)

Update date:2022-07-31

Topics:

Authors:

Takemoto, Yoshiji

Matsumoto, Teruyo

Ito, Yoshio

Terashima, Shiro

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Article abstract of DOI:10.1016/S0040-4039(00)94374-0

The title synthesis could be accomplished by employing highly stereoselective aldol reaction of O-methyl-O-trimethylsilyl ketene acetal with the (S)-α-amido aldehyde (2) in the presence of titanium (IV) chloride as a key step.

Full text of DOI:10.1016/S0040-4039(00)94374-0

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Product name:Carbamic acid, [1-(hydroxymethyl)-2-phenylethyl]-, 1-methylethyl ester, (S)-

Cas No:124995-02-4

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