TRANSFORMATION OF N-TOSYL-2-(1,3-BUTADIENYL)AZIRIDINE INTO N-TOSYL-2-ETHENYL-3-PYRROLINE.

DOI: 10.1016/S0040-4020(01)80135-6

Source and publish data:

Tetrahedron p. 3089 - 3098 (1989)

Update date:2022-09-26

Topics:

Authors:

Fugami, Keigo

Miura, Katsukiyo

Morizawa, Yoshitomi

Oshima, Koichiro

Utimoto, Kiitiro

Nozaki, Hitosi

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Article abstract of DOI:10.1016/S0040-4020(01)80135-6

1,3-Butadienylaziridines or 1,3-butadienylazetidines activated by N-tosyl group smoothly rearrange to vinylpyrroline derivatives or vinylpiperidines in the presence of a catalytic amount of Pd(PPh3)4.Triphenyltin radical induced rearrangement of title compounds is also described.

Full text of DOI:10.1016/S0040-4020(01)80135-6

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