Synthesis of methyl 2,3-diaryl-3-methoxypropanoates by oxidative rearrangement of chalcones using hypervalent iodine reagents in trimethyl orthoformate

DOI: 10.1055/s-1990-27083

Source and publish data:

Synthesis p. 1025 - 1026 (1990)

Update date:2022-09-26

Topics:

Authors:

Singh Singh

Garg Garg

Kapoor Kapoor

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1990-27083

A diastereoselective synthesis of methyl 2,3-diaryl-3-methoxypropanoates 8a-f by oxidative rearrangement of chalcones 1a-f using (diacetoxyiodo)benzene and hydroxy(tosyloxy)iodobenzene in trimethyl orthoformate is described.

Full text of DOI:10.1055/s-1990-27083

Products guided by the article

Product name:Benzene, 1,1'-(3,3-dimethoxy-1-propene-1,3-diyl)bis-, (E)-

Cas No:125288-34-8

R&D Labs maybe for 125288-34-8

Ji'nan Orgachem Pharmaceutical Co.,Ltd

Contact:+86-531-82687810

Address:Jinan
NEWSTAR CHEM ENTERPRISE LTD.

Contact:0572-2722882

Address:1201,F3,xinghuibandao,
sichuan tiancai fine co LTD.

website:http://www.tcfinechem.com/

Contact:18681346930

Address:baifu town,whou district
Hebei Tete Trade Co., Ltd.

Contact:86-311-83160559

Address:shijiazhuang
Weihao Chemtech (ChangZhou) Co., Ltd.(expird)

Contact:051989185693

Address:NO 217 huangshan Rd ,Changzhou

Relevant to this article

Syntheses, structure characterisation and X-ray structures of the complexes Ru₃(CO)₁₁L [L = Ph₂P(C₆H ₄Me-p), Ph₂PC₆F₅, P(C ₆H₄Cl-p)₃,

Doi:10.1016/j.poly.2010.06.013
(2010)
Asymmetric total synthesis of rugulactone, an α-pyrone from Cryptocarya rugulosa

Doi:10.1055/s-0029-1218836
(2010)
Scaled-up transition-metal-catalyzed cross-coupling reactions of thioether-substituted N-heterocycles with organozinc reagents

Doi:10.1055/s-0030-1258145
(2010)
A unique approach to the concise synthesis of highly optically active spirooxazolines and the discovery of a more potent oxindole-type phytoalexin analogue

Doi:10.1021/ja106349m
(2010)
Coupling the petasis condensation to an iron(III) chloride-promoted cascade provides a short synthesis of Relenza congeners

Doi:10.1021/ol102326b
(2010)
Strained dimethyl 2-(bromoselanyl)-5-tert-butylisophthalate: A reactive precursor for the synthesis of ebselen analogs

Doi:10.1016/j.tetlet.2011.10.067
(2011)

Article Doi