An Efficient Route to Both Enantiomers of N-(p-Tolylsulfonyl)-benzenesulfonimidamide and Their Use for Asymmetric Allylic Amination of Olefins

Article abstract of DOI:10.1246/bcsj.62.1167

The chiral compounds (R)- and (S)-N-(p-tolylsulfonyl)benzenesulfonimidamide have been prepared effiently from N-(p-tolylsulfonyl)benzenesulfonimidoyl chloride and both enenatiomers were transformed into chiral selenium diimide reagents, (S)- and (R)-N,N'-